有机方法Hypervalent Iodine as Terminal Oxidant in Wacker-Type Oxidation of Terminal Olefins to Methyl KetoneA mimic of the Wacker process for C═O bond formation in terminal olefins can be initiated by a com...chem2017-05-084.4W #甲基酮
有机方法Cu-Mediated Chemoselective Trifluoromethylation of Benzyl BromidesCopper-mediated chemoselective trifluoromethylation at the benzylic position by the use of shelf-s...chem2017-05-085.6W #三氟甲基
有机方法Chemoselective Suzuki Coupling of Diborylmethane for Facile Synthesis of BenzylboronatesThe chemoselective Pd-catalyzed Suzuki–Miyaura cross-coupling reaction using a diborylmethane is r...chem2017-05-034.4W #benzylboronates
有机方法Rate Enhanced Olefin Cross-Metathesis Reactions: The Copper Iodide EffectCopper iodide has been shown to be an effective cocatalyst for the olefin cross-metathesis reactio...chem2017-04-114.9W
有机方法Corey–Nicolaou大环内酯化反应 ω-羟基酸或更长链的羟基酸通过2,2’-吡啶二硫化物处理得到大环内酯的反应。此反应也被称为Corey–Nicolaou双活化法。环化阶段通常需要加热回流。加入AgBF4可以活化吡啶硫酯...chem2017-04-076.1W #macro-lactones
有机方法Shiina大环内酯化反应 羟基羧酸利用2-甲基-6-硝基苯甲酸酐(MNBA; Shiina试剂 ，催化量的缩合剂(DMAP, DMAPO, PPY, etc 和三级胺，在温和的条件下进行大环内酯化的反应。此反应是东京理科大...chem2017-04-075.9W #macro-lactones
有机方法Yamaguchi酯化反应该反应最早是由日本九州大学的Masaru Yamaguchi在1979年报道的。 羧酸和2,4,6-三氯苯甲酰氯作用生成混酐使羧酸得以活化，继而在DMAP的催化下与醇反应生成酯。...chem2017-04-077.1W #macro-lactones
有机方法Valent titanium Reductive Cleavage of Sulfonamides and Sulfonates A low-valent titanium generated in situ from Ti(O-i-Pr 4, Me3SiCl, and Mg powder in THF reacted wi...chem2017-03-274.2W #Sulfonamide
有机方法Palladium-Catalyzed Cyanomethylation of Aryl Halides through Domino Suzuki Coupling–Isoxazole FragmeA one-pot protocol for the cyanomethylation of aryl halides through a palladium-catalyzed reaction...chem2017-03-234.3W
有机方法Petasis Mannich reactionThe Petasis reaction (alternatively called the Petasis borono–Mannich (PBM reaction is the chemica...chem2017-02-184.5W
