Kulinkovich反应Kulinkovich反应，又称Kulinkovich环丙烷化反应，是指在异丙醇钛(Ⅳ [Ti(OiPr 4] 催化下，乙基或更高级的格氏试剂（有β-氢）与酯反应生成环丙醇衍生物的反应。由 ...有机方法2021-07-246.9W #人名反应
无过渡金属参与DMAP促进的酰胺与有机硼酸的酯化反应酰胺作为一类非常重要的骨架分子广泛存在于天然产物、蛋白质和其他重要的功能有机分子中。在过去的几十年里，发展各种新方法来构建酰胺骨架化合物引起了人们的广泛关注。相比之下，由酰胺骨架化合物转化为其他官能团...有机方法2021-07-106.2W #DMAP
催化量的甲醇钠选择性脱除Boc保护基A highly selective and efficient deprotection of the N‐t‐butoxy carbonyl (N‐Boc group on indoles,...有机方法2021-07-046.4W
吲哚3位上氰基To a solution of the appropriate indoles 3a-d (6.8 mmol in anhydrous acetonitrile (6.0 mL ,chloro...有机方法2021-07-015.7W #CSI
Chan–Lam Amination of Secondary and Tertiary Benzylic Boronic EstersWe report a Chan–Lam coupling reaction of benzylic and allylic boronic esters with primary and sec...有机方法2021-06-275.6W #Cu(OAc)2 #Chan–Lam
Stereoselective Oxidative Cyclization of N-Allyl Benzamides to Oxaz(ol)inesThis study presents an enantioselective oxidative cyclization of N-allyl carboxamides via a chiral...有机方法2021-06-237.5W
格氏试剂与NFSI快速制备F化物A common way to prepare aryl fluorides is through lithium-halogen exchange, followed by trapping w...有机方法2021-06-097.9W
插羰反应制备羧酸衍生物芳基和烯基卤化物在温和条件下的钯催化插羰反应是合成羧酸及其衍生物的非常有用的合成方法。反应机理是芳基和烯基卤化物先和Pd(0 发生氧化加成反应生成芳基或烯基钯配合物，然后CO插入到钯--碳键之间，还原...有机方法2021-06-0112.2W
Accessing Aliphatic Amines in C–C Cross-Couplings by Visible Light/Nickel Dual CatalysisA general aminoalkylation of aryl halides was developed, overcoming intolerance of free amines in...有机方法2021-05-306.0W #photoredox
